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An experimental study of particulate matter and volatile organic compounds (VOCs) emissions was conducted on a direct injection gasoline (DIG) engine and a port fuel injection (PFI) engine which both were produced by Chinese original equipment manufacturers (OEMs) to investigate the impact of fuel properties from Chinese market on particulate and VOCs emissions from modern gasoline vehicles. The study in this paper is just the first step of the work which is to investigate the impact of gasoline fuel properties and light duty vehicle technologies on the primary and secondary emissions, which are the sources of particulate matter 2.5 (PM2.5) in the atmosphere in China. It is expected through the whole work to provide some suggestions and guidelines on how to improve air quality and mediate severe haze pollution in China through fuel quality control and vehicle technology advances.

Spray atomization, spray-wall impingement, and mixture formation are key factors in affecting the particulate matter (PM) emission in gasoline direct injection (GDI) engines. Current knowledge of wall-wetting phenomenon and mixture formation are mostly based on the studies that the fuel is injected at ordinary temperature and various ambient conditions. In the real GDI engine, the fuel pipe and injector are always heated up by the pump and the engine body, especially at hot engine conditions, thus the fuel temperature is always higher than the ordinary temperature, and the relevant research is still limited. The aim of this study is to numerically investigate the spray, spray-wall impingement, and mixture formation characteristics under different fuel temperature conditions, so as to provide theoretical support in optimizing the combustion performance and further reducing the PM emission of GDI engines.

A new combustion mode namely multiple premixed compression ignition (MPCI) for gasoline engines was proposed. The MPCI mode can be realized by two or more times gasoline injections into cylinder with a high pressure around the compression TDC and featured with a premixed combustion after each injection in the cylinder, which is different from the existed gasoline direct injection compression ignition (GDICI) modes such as homogeneous charge compression ignition (HCCI) mode with gasoline injection occurred in intake stroke, and partially premixed compression ignition (PPCI) mode with multiple gasoline injections in intake and compression strokes before the start of combustion (SOC). Therefore the spray and combustion of the MPCI mode are alternatively occurred as "spray-combustion-spray-combustion" near the TDC, rather than "spray-spray-combustion" sequence as traditional PPCI gasoline engines.

The urea NOx selective catalytic reduction (SCR) is an effective technique for the reduction of NOx emitted from diesel engines. Urea spray quality has significant effect on NOx conversion efficiency. The droplet diameter and velocity distribution of air-assisted and airless urea injection systems were obtained by particle dynamics analyzer (PDA) measurement under different spray injection flow rates. It was found that the atomization quality of air-assisted urea injection system is better than that of airless urea injection system. The penetration and spray cone angle were also investigated by high-speed photography. Especially the spray characteristics of air-assisted urea injection system were measured in the constant-volume-bomb by high-speed photography. The atomization and evaporation of airless urea injection systems were modeled using computational fluid dynamics (CFD) based on the experimental results. The numerical model was validated by the experimental results.

Gasoline direct injection engines can greatly improve the fuel economy, but the idea mixture distribution cannot be easily controlled. In this paper, the linearized instability sheet atomization (LISA) and large eddy simulation (LES) implemented into KIVA-3V code were used to study the gasoline hollow cone spray process for gasoline direct injection (GDI) in a constant volume vessel. The three-dimensional results show that the LISA model can effectively simulate the gasoline hollow cone spray and obtain the string structure compared to the experiment data. And the velocity interpolation method can reduce the grid dependency of spray simulation. Using dense grid (about 8 million cells) in LES and RANS all can obtain the good spray tip penetration and width. Unlike diesel spray, for gasoline spray there are not big difference between the results using LES and RANS. In additional the ambient pressure significantly influence the gasoline spray shape.

2, 5-Dimethylfuran (DMF) has been receiving increasing interest as a potential alternative fuel to fossil fuels, owing to the recent development of new production technology. However, the influence of DMF properties on the in-cylinder fuel spray and its evaporation, subsequent combustion processes as well as emission formation in current gasoline direct injection (GDI) engines is still not well understood, due to the lack of comprehensive understanding of its physical and chemical characteristics. To better understand the spray characteristics of DMF and its application to the IC engine, the fuel sprays of DMF and gasoline were investigated by experimental and computational methods. The shadowgraph and Phase Doppler Particle Analyzer (PDPA) techniques were used for measuring spray penetration, droplet velocity and size distribution of both fuels.

HCCI combustion was studied in a 4-stroke gasoline engine with a direct injection system. The electronically controlled two-stage gasoline injection and spark ignition system were adopted to control the mixture formation, ignition timing and combustion rate in HCCI engine. The engine could be operated in HCCI combustion mode in a range of load from 1 to 5 bar IMEP and operated in SI combustion mode up to load of 8 bar IMEP. The HCCI combustion characteristics were investigated under different A/F ratios, engine speeds, starts of injection, as well as spark ignition enabled or not. The test results reveal the HCCI combustion features as a high-pressure gradient after ignition and has advantages in high thermal efficiency and low NOx emissions over SI combustion. At the part load of 1400rpm and IMEP of 3.5bar, ISFC in HCCI mode is 25% lower and NOx emissions is 95% lower than that in SI mode.

In order to enhance the thermal efficiency of gasoline engines, a combustion mode namely Homogeneous Charge Induced Ignition (HCII) was introduced and examined in this paper. Port-injected gasoline was used as the main fuel and formed a homogeneous charge in the cylinder. Diesel was used as the pilot fuel, directly injected into the cylinder, and self-ignited and this induced the ignition of the premixed gasoline-air charge. The images of HCII combustion process were taken on an optical engine through a high-speed CMOS camera. The multi-point induced ignition phenomena were observed and the parameters like flame luminance, ignition delay and combustion duration were analyzed by image analysis. The result shows that as the gasoline/diesel ratio increases with a fixed low pilot amount, the ignition delay increases, the initial ignition area extends from the center towards the periphery of the combustion chamber, and the combustion velocity increased.

Gasoline Direct Injection (GDI) engines developed at nineties of the twentieth century can greatly improve the fuel economy. But the combustion chamber design and mixture control of the engines are very complex compared with Port Fuel Injection (PFI) gasoline engines. A two-stage gasoline direct injection (TSGDI) combustion system is developed and aimed to solve the problem of the complexity. Two-stage fuel injection and flexible injection timings are adopted as main means to form reasonable stratified mixture in the cylinder. A simple combustion chamber and helical intake port are designed to assist the mixture's stable combustion, which reduces the difficulties of the combustion system design. Systematical simulation and experimental studies of the effects of injection strategies such as different first,second injection timings and injection ratios, on the mixture formation processes and engine performanc are made in detail.

Diesel particulate filter (DPF) is indispensable for diesel engines to meet the increasingly stringent emission regulations. Both the peak temperature and the maximum temperature gradient of the DPF during active regeneration should be well controlled in order to enhance the reliability and durability of the filter. In this paper, the temperature field of the DPF during active regeneration with hydrocarbon (HC) injection was investigated with engine bench tests and numerical simulation. For the experimental study, 24 thermocouples were inserted into the DPF channels to measure the inner temperature of the filter to capture its temperature field, and the circumferential, axial and radial distribution of the filter temperature was analyzed to understand the DPF temperature field behavior during active regeneration.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

Diesel particulate filter (DPF) is necessary for diesel engines to meet the increasingly stringent emission regulations. Many studies have demonstrated that the lubricant derived ash has a significant effect on DPF pressure drop and engine fuel economy, and this effect becomes more and more severe with the increasing of operating hours of the DPF because the ash accumulated in the DPF cannot be removed by regeneration. It is reported that most of the DPFs operated with more ash than soot in the filter for more than three quarters of the time during its lifetime [1]. In order to mitigate this problem, the original engine manufacturers (OEM) tend to use an oversized DPF for the engine. However, it will increase the costs of the DPF and reduce the compactness of the engine aftertreatment system.

Urea-based selective catalytic reduction (SCR) of nitric oxides (NOx) is a key technology for heavy-duty diesel engines to achieve the increasingly stringent NOx emission standards. The aqueous urea injection control is critical for urea-SCR systems in order to achieve high NOx conversion efficiency while restricting the tailpipe ammonia (NH3) slip. For Euro VI emission regulation, an advanced control strategy is essential for SCR systems since its NOx emission limits are tighter and test procedure are more stringent compared to Euro IV and Euro V. The complex chemical kinetics of the SCR process has motivated model-based control design approaches. However, the model is too complex to allow real-time implementation. Therefore, it is very important to have a reduced order model for SCR control system.

A study of Multiple Premixed Compression Ignition (MPCI) with heavy naphtha is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the net indicated mean effective pressure (IMEP) from 0.5MPa to 0.9MPa. Commercial diesel is also tested with the single injection for reference. The combustion and emissions characteristics of the heavy naphtha are investigated by sweeping the first (−200 ∼ −20 deg ATDC) and the second injection timing (−5 ∼ 15 deg ATDC) with an injection split ratio of 50/50. The results show that compared with diesel combustion, the naphtha MPCI can reduce NOx, soot emissions and particle number simultaneously while maintaining or achieving even higher indicated thermal efficiency. A low pressure rise rate can be achieved due to the two-stage combustion character of the MPCI mode but with the penalty of high HC and CO emissions, especially at 0.5MPa IMEP.

Selective catalytic reduction (SCR) has been demonstrated as one of the most promising technologies to reduce NOx emissions from heavy-duty diesel engines. To meet the Euro VI regulations, the SCR system should achieve high NOx reduction efficiency even at low temperature. In the SCR system, NH3 is usually supplied by the injection of urea water solution (UWS), therefore it is important to improve the evaporation and decomposition efficiency of UWS at low temperature and minimize urea deposits. In this study, the UWS spray, urea decomposition, and the UWS impingement on pipe wall at low temperature were investigated based on an engine test bench and computational fluid dynamics (CFD) code. The decomposition of urea and deposits was analyzed using thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC) and fourier transform infrared spectroscopy (FTIR).

An experimental study of particulate matter (PM) emission was conducted on four cars from Chinese market. Three cars were powered by gasoline direct injection (GDI) engines and one car was powered by a port fuel injection (PFI) engine. Particulate mass, number and size distribution were measured based on a chassis dynamometer over new European driving cycle (NEDC). The particulate emission behaviors during cold start and hot start NEDCs were compared to understand how the running conditions influence particulate emission. Three kinds of gasoline with RON 91.9, 94.0 and 97.4 were tested to find the impact of RON on particulate emission. Because of time and facilities constraints, only one cold/hot start NEDC was conducted for every vehicle fueled with every fuel. The test results showed that more particles were emitted during cold start condition (first 200s in NEDC). Compared with cold start NEDC, the particulate mass and number of hot start NEDC decreased by a wide margin.

A study of Multiple Premixed Compression Ignition (MPCI) with mixtures of gasoline and diesel is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the same fuel mass per cycle. By keeping the same intake pressure and EGR ratio, the influence of different blending ratios in gasoline and diesel mixtures (90vol%, 80vol% and 70vol% gasoline) is investigated. Combustion and emission characteristics are compared by sweeping the first (−95 ∼ −35deg ATDC) and the second injection timing (−1 ∼ 9deg ATDC) with an injection split ratio of 80/20 and an injection pressure of 80MPa. The results show that compared with diesel combustion, the gasoline and diesel mixtures can reduce NOx and soot emissions simultaneously while maintaining or achieving even higher indicated thermal efficiency, but the HC and CO emissions are high for the mixtures.

The primary breakup of a planar liquid sheet produced by an air-blast atomizer was studied through numerical simulations, in order to reveal physical mechanisms involved during this process. The reliability of simulations was verified by comparing the macroscopic parameters, e.g. breakup time and spatial growth rate, with experimental data. Shear instability and RT (Rayleigh-Taylor) instability were found to play important roles during the primary breakup. By analyzing the acceleration of a fluid parcel within liquid sheet using Discrete Particle Method, and measuring the wave length of transverse unstable wave, RT instability was found to be partially responsible for transverse instability. The predictions of LISA (Linearized Instability Sheet Atomization) model on breakup time were compared to experiments, and obvious differences were found to exist.

Little research has been done on spray characteristics of 2,5-dimethylfuran (DMF), since the breakthrough in its production method as an alternative fuel candidate. In this paper, the spray characteristics of pure fuels (DMF, Isooctane) and DMF-Isooctane blends under different ambient pressures (1 bar, 3 bar and 7 bar) and injection pressures (50 bar, 100 bar and 150 bar) were studied using Phase Doppler Particle Analyzer (PDPA) and high speed imaging. Droplet velocity, size distribution, spray angle and penetration of sprays were examined. Based on the results, DMF had larger SMD and penetration length than isooctane. The surface tension of fuel strongly influenced spray characteristics. Increasing the surface tension by 26 % resulted in 12 % increase in SMD. Higher ambient pressure increased the drag force, but SMD was not influenced by the increased drag force. However, the increased ambient pressure reduced the injection velocity and We number resulting in higher SMD.

This paper studied the knock combustion process in gasoline HCCI engines. The complex chemical kinetics was implemented into the three-dimensional CFD code with LES (Large eddy simulation) to study the origin of the knock phenomena in HCCI combustion process. The model was validated using the experimental data from the cylinder pressure measurement. 3D-CFD with LES method gives detailed turbulence, species, temperature and pressure distribution during the gasoline HCCI combustion process. The simulation results indicate that HCCI engine knock originates from the random multipoint auto-ignition in the combustion chamber due to the slight inhomogeneity. It is induced by the significantly different heat release rate of high temperature oxidation (HTO) and low temperature oxidation (LTO) and their interactions.